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CSIR-NET Dec-2015 Q3

Vishnu Mestry Monday, 29 August 2016 No Comments

The oxidizing power of [CrO4]2- , [MnO4]2- , and [FeO4]2- follows the order
(1.) [CrO4]2- < [MnO4]2- < [FeO4]2-
(2.) [FeO4]2- < [MnO4]2- < [CrO4]2-
(3.) [MnO4]2- < [FeO4]2- < [CrO4]2-
(4.) [CrO4]2- < [FeO4]2- < 
[MnO4]2-

Soln (1) 

The more an element is electronegative, the higher will be is oxidizing power. More electronegative is Fe (26), followed by Mn (25) and then Cr (24), so the order for the oxidizing power of those elements : Fe>Mn>Cr. 
Since oxidation number is same (VI) in all three metals.
[CrO4]2- < [MnO4]2- < [FeO4]2-
Reference https://www.physicsforums.com/threads/a-problem-about-oxdizing-power.827918/
Vishnu Mestry

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