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CSIR UGC NET Dec15 Q. 11

Vishnu Mestry Tuesday, 11 October 2016 1 Comment
The order of increasing Brønsted acidity for boron hydrides is

A. B5H9 < B6H10 < B10H14

B. B10H14 < B5H9 < B6H10

C. B6H10 < B10H14 < B5H9

D. B10H14 < B6H10< B5H9

Soln : 
A. B5H9 < B6H10 < B10H14

Acidity of boron hydride depends on the size of borane greater the sizes higher will be the acidity. This is because the negative charge, formed upon deprotonation, can be better delocalized over a large anion with many boron atoms than over a small one.
Vishnu Mestry

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1 comment:

  1. Unknown19 November 2019 at 08:20

    Thank u for the solutions... Saved my time a lot...I request to give the solutions of previous papers

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